A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ2 S,S′]zinc(II)]-μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3 S,S′:N] 4-methylpyridine hemisolvate]
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چکیده
منابع مشابه
A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ2 S,S′]zinc(II)]-μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3 S,S′:N] 4-methylpyridine hemisolvate]
The title compound, {[Zn(C9H11N2S2)2]·0.5C6H7N} n , comprises two independent, but chemically similar, Zn[S2CN(Et)CH2py]2 residues and a 4-methyl-pyridine solvent mol-ecule in the asymmetric unit. The Zn-containing units are connected into a one-dimensional coordination polymer (zigzag topology) propagating in the [010] direction, with one di-thio-carbamate ligand bridging in a μ2-κ3 mode, empl...
متن کاملA two-dimensional coordination polymer: poly[[bis[μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3 N:S,S′]cadmium(II)] 3-methylpyridine monosolvate]
The title compound, {[Cd(C9H11N2S2)2]·C6H7N} n , features two μ2-κ3-di-thio-carbamate ligands each of which chelates one CdII atom, via the S atoms, while simultaneously bridging to another via the pyridyl-N atom. The result is a two-dimensional coordination polymer extending parallel to the ab plane with square channels along the b axis. The CdII atom geometry is based on a distorted cis-N2S4 ...
متن کاملCrystal structure of an HgII coordination polymer with an unsymmetrical dipyridyl ligand: catena-poly[[[dichloridomercury(II)]-μ-N-(pyridin-4-ylmethyl)pyridin-3-amine-κ2 N:N′] chloroform hemisolvate]
The asymmetric unit of the title compound, {[HgLCl2]·0.5CHCl3} n (L = N-(pyridin-4-ylmeth-yl)pyridin-3-amine, C11H11N3), contains one HgII ion, one bridging L ligand, two chloride ligands and a chloro-form solvent mol-ecule with half-occupancy that is disordered about a crystallographic twofold rotation axis. Each HgII ion is coordinated by two pyridine N atoms from two symmetry-related L ligan...
متن کاملPoly[[[μ3-(E)-N-(pyridin-4-ylmethylidene)hydroxylaminato-κ3 O:N:N′][μ2-(E)-N-(pyridin-4-ylmethylidene)hydroxylamine-κ2 N:N′][(E)-N-(pyridin-4-ylmethylidene-κN)hydroxylamine]disilver(I)] nitrate]
The title coordination polymer, {[Ag2(C6H5N2O)(C6H6N2O)2]NO3} n , features a deprotonated N-(pyridin-4-yl-methyl-idene)hy-droxy-laminate anion and two neutral N-(pyridin-4-yl-methyl-idene)hydroxyl-amine mol-ecules in the asymmetric unit. The anion connects three Ag(I) atoms through its O and two N-donor atoms. One neutral ligand functions in a monodentate mode; the other functions in a bridging...
متن کاملcatena-Poly[[diaquabis(formato-κO)cobalt(II)]-μ2-2,6-bis(pyridin-4-yl)-4,4′-bipyridine-κ2 N 2:N 6]
In the title complex, [Co(CHO(2))(2)(C(20)H(14)N(4))(H(2)O)(2)](n), the Co(II) ion, lying on an inversion center, is six-coordinated by two O atoms from two monodentate formate ligands, two N atoms from two 2,6-bis-(pyridin-4-yl)-4,4'-bipyridine (4-pybpy) ligands and two water mol-ecules, displaying an octa-hedral geometry. The 4-pybpy ligand, having a twofold rotation axis, functions in a brid...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Crystallographic Communications
سال: 2017
ISSN: 2056-9890
DOI: 10.1107/s2056989017010179